AB INITIO INVESTIGATION OF 12-CROWN-4 AND BENZO-12-CROWN-4 COMPLEXES WITH Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>, Zn<sup>2+</sup>, Cd<sup>2+</sup>, AND Hg<sup>2+</sup>
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چکیده
منابع مشابه
Spectroscopic Studies on Charge-Transfer Complexation of Iodine with Dibenzo-15-crown-5 and Benzo-12-crown-4 in Chloroform, Dichloromethane and 1,2-Dichloroethane
The formation of charge-transfer complexation between dibenzo-15-crown-5 (DB15C5) and benzo-12-crown-4 (B12C4) (Donor) and iodine is investigated spectrophotometrically in three chlorinated solvents,chloroform, dichloromethane (DCM) and 1,2-dichloroethane (DCE) solution at 25°C. The change in polarityof the solvent also doesn’t affect the stoichiometry of the complexes. Values of formation cons...
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Silica coated magnetite nanoparticles were covalent grafted with 3-aminopropyl trimethoxysilane to give APTSCMNPs. Reaction of the resulted nanomaterial with 4-formyl benzo-12-crown-4 ether afforded FB12C4/APTSMNPs nanocomposite material in which the crown ether moiety was attached through propyl chain spacer. Characterization of the prepared nanocomposite was performed wit...
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The new compound [K–(12C4)2]2[K–12C4]2[Sn9]·4en (1), where 12C4 is 12-crown-4 polyether, was crystallized from an ethylenediamine solution of an intermetallic precursor with nominal composition K4Li2Sn8. The structure of the compound (orthorhombic, Cmca, a = 21.763(4), b = 16.030(3), c = 51.85(1) Å, Z = 8) contains isolated deltahedral clusters of [Sn9]4−. The clusters are of Cs symmetry and ar...
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متن کاملorganic-inorganic hybrid nanomaterials prepared from 4- formyl benzo-12-crown-4-ether and silica coated magnetite nanoparticles
silica coated magnetite nanoparticles were covalent grafted with 3-aminopropyl trimethoxysilane to give aptscmnps. reaction of the resulted nanomaterial with 4-formyl benzo-12-crown-4 ether afforded fb12c4/aptsmnps nanocomposite material in which the crown ether moiety was attached through propyl chain spacer. characterization of the prepared nanocomposite was performed wit...
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ژورنال
عنوان ژورنال: Indonesian Journal of Chemistry
سال: 2010
ISSN: 2460-1578,1411-9420
DOI: 10.22146/ijc.21488